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- W2005177189 abstract "X-ray scattering studies on aligned films of binary mixtures of the normal alkanes ${mathrm{C}}_{23}$${mathrm{H}}_{48}$ and ${mathrm{C}}_{28}$${mathrm{H}}_{58}$ reveal, for the first time in such materials, the existence of a new equilibrium phase having the symmetry of a smectic crystal, possibly a hexatic. This phase occurs between the hexagonally packed ${mathit{R}}_{mathrm{II}}$ and the lower-temperature orthorhombic ${mathit{R}}_{mathrm{I}}$, plastic crystalline, layered, rotator phases. We argue that this loss of order is due to local distortion fluctuations in the hexagonal phase. Furthermore, we have identified an ABC-to-ABAB restacking transition within the ordered ${mathit{R}}_{mathrm{II}}$ phase." @default.
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- W2005177189 date "1992-01-27" @default.
- W2005177189 modified "2023-10-17" @default.
- W2005177189 title "Novel phase behavior in normal alkanes" @default.
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- W2005177189 doi "https://doi.org/10.1103/physrevlett.68.492" @default.
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