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• W2005177511 abstract "A synthesis of the title ligand is described in which the key step is the dilithiation of 1,1'-bis(dimethylaminomethyl)-3,3'-biindolyl and electrophilic trapping with ClPPh2. Concomitant N-deprotection and resolution with bis[(R)-dimethyl(1-(1-naphthyl) ethylaminato-C2,N)palladium chloride] led to selective recovery of the S-enantiomer. The N-dimethylaminomethyl-substituted biindolyl, but not the parent compound, showed strongly second-order behaviour for 13C NMR peaks in the region of the phosphorus atom due to a desymmetrising 13C-induced isotope shift of the 31P resonance." @default.
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• W2005177511 date "1996-01-01" @default.
• W2005177511 modified "2023-10-18" @default.
• W2005177511 title "Synthesis and resolution of 2,2'-bis-diphenylphosphino [3,3']biindolyl ; a new atropisomeric ligand for transition metal catalysis" @default.
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• W2005177511 doi "https://doi.org/10.1016/0957-4166(95)00447-5" @default.
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