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- W2005187654 abstract "Tropospheric concentrations of nocturnal NO 2 measured at our rural site in New Zealand (45°S, 170°E) are presented. We also describe the long path spectroscopic absorption technique used. The system features a beam splitter just before the exit slit of a scanning monochromator, and the broad spectral band signal seen at a second detector is used to remove the effect of amplitude modulations caused by atmospheric flicker. A signal ratioing technique produces nearly 2 orders of magnitude improvement in this noise. With a one hour observation period detection thresholds of 20 ppt have been achieved from absorptions over a 9.2 km path. The results display a wide range of mixing ratios from the detection threshold, up to in excess of 1 ppb on isolated days. A strong absorption feature at 442.6 nm is identified as a water vapour absorption, and the absorption cross section is found to be (3.1±0.3) × 10 −26 cm² molecule −1 at 0.5 nm resolution." @default.
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- W2005187654 date "1984-01-01" @default.
- W2005187654 modified "2023-10-10" @default.
- W2005187654 title "Long-path absorption measurements of tropospheric NO<sub>2</sub>in rural New Zealand" @default.
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- W2005187654 doi "https://doi.org/10.1029/gl011i001p00069" @default.
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