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- W2005189002 abstract "Complexes of cobalt(II) trifluoroacetate with pyridine and alkylpyridine ligands of stoicheiometries ML4T2 and ML2T2 have been investigated in solution by 1H and 19F n.m.r. spectroscopy. In deuteriochloroform solution, cis–trans isomeric equilibria were detected for both series of complexes. Rapid cis–trans exchange occurred at ambient temperatures but became slow on the n.m.r. time scale below ca. 0 °C for ML2T2 complexes and below ca. –50 °C for ML4T2 complexes. In the ML4T2 series, intermediate species were detected between ca. 0 °C and ca. –40 °C. In hexadeuterioacetone solution, a number of polymeric species were detected. Some evidence has also been obtained for a rapid intramolecular scrambling of ligands occurring in these complexes even at temperatures below –60 °C." @default.
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- W2005189002 date "1974-01-01" @default.
- W2005189002 modified "2023-09-26" @default.
- W2005189002 title "Trifluoroacetate complexes of cobalt(II), nickel(II), and copper(II) with pyridine-type ligands. Part III. Nuclear magnetic resonance studies of cobalt(II) complexes in solution" @default.
- W2005189002 doi "https://doi.org/10.1039/dt9740000870" @default.
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