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- W2005201727 abstract "The two-dimensional polyhedral anion network melilites La1+xSr1−xGa3O7+0.5x exhibit interstitial oxide ion conductivity. The solid solution is shown to extend to x = 0.64, and the variation of the conductivity with x is investigated. At high temperatures, all of these compounds adopt the typical tetragonal melilite structure. When x > 0.6, cooling below 600 °C results in a reversible phase transition to an orthorhombic structure which reduces the ionic conductivity. Quenching experiments have shown the tetragonal structure has a higher conductivity compared to the orthorhombic structure of the same composition. Short-range order effects associated with this transition exercise an important influence on the composition- and temperature-dependence of the conductivity." @default.
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- W2005201727 date "2010-03-30" @default.
- W2005201727 modified "2023-10-11" @default.
- W2005201727 title "Phase Stability Control of Interstitial Oxide Ion Conductivity in the La<sub>1+<i>x</i></sub>Sr<sub>1−<i>x</i></sub>Ga<sub>3</sub>O<sub>7+<i>x</i>/2</sub> Melilite Family" @default.
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- W2005201727 doi "https://doi.org/10.1021/cm903132w" @default.
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