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• W2005205429 abstract "Abstract Cubic TmPd 3 S 4 is in the series of rare-earth (R) palladium bronzes, RPd 3 S 4 , which is an attractive platform for multipolar interaction systems. We previously reported that, in RPd 3 S 4 , only TmPd 3 S 4 shows a Jahn–Teller-like phase transition at approximately 200 K, accompanying a structure modulation. Our present electron diffraction study, however, has revealed that the expected modulation does not occur. We reexamined the crystal growth conditions and found crystal polymorphism with the cubic and monoclinic structures. The phase transition at approximately 200 K can be interpreted as a phase separation into the cubic and monoclinic phases. Single-phase monoclinic TmPd 3 S 4 was successfully obtained at room temperature. The monoclinic TmPd 3 S 4 is metallic and shows no magnetic phase transition down to 0.6 K." @default.
• W2005205429 created "2016-06-24" @default.
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• W2005205429 date "2013-01-01" @default.
• W2005205429 modified "2023-10-14" @default.
• W2005205429 title "Crystal polymorphism in TmPd3S4" @default.
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• W2005205429 doi "https://doi.org/10.1016/j.rinp.2013.05.005" @default.
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