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- W2005220350 abstract "A first−order theory for the calculation of Helmholtz free energy differences is used to calculate the free energy (relative to an ideal gas at the same temperature and number density) of N2, CO, and their equimolar mixture. Results show that the superposition of the quadrupole−quadrupole interactions on the Lennard−Jones interactions does not provide an intermolecular potential model that quantitatively describes the mixing thermodynamics. However, such a model does appear to be an effective pair potential for CO. Additional calculations are presented that further establish the accuracy of the selected first−order theory." @default.
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- W2005220350 title "Quadrupole–quadrupole interactions in CO and N2: Effect on the thermodynamics of mixing" @default.
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- W2005220350 doi "https://doi.org/10.1063/1.430464" @default.
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