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- W2005220576 abstract "Polymethylsilane (PMS) with a general formula [−(CH3SiH)1-y−(CH3Si)y−]n has been synthesized by Würtz type polycondensation of methyldichlorosilane. Copolycondensation with dimethylchlorosilane was realized in an attempt to control the viscosity of the PMS. Thermal reactions at 230 °C with small amounts (1 wt %) of boron derivatives such as B[OSi(CH3)3]3 serve to cross-link this Si−H-containing organosilicon polymer. As a result, when the products of these reactions are pyrolyzed at 1000 °C under argon, the ceramic residue yields are increased considerably over those obtained with the original polymers." @default.
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- W2005220576 date "1998-01-19" @default.
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- W2005220576 title "Borate-Catalyzed Thermolysis of Polymethylsilane" @default.
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- W2005220576 doi "https://doi.org/10.1021/cm970443a" @default.
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