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- W2005228774 abstract "The selective hydrogenation of α-methylcinnamaldehydes to the hydrocinnamaldehydes, catalyzed by cobalt carbonyl and a limited amount of amines, has been investigated. The addition of such amines as diisopropylamine, diethanolamine, tributylamine, triethylamine, and pyridine showed a remarkable selectivity and gave the desired α-methylhydrocinnamaldehydes in 96.4–91.5% theoretical yields. Especially, diisopropylamine gave the best selectivity, in it the yields of p-t-butyl-α-methylhydrocinnamaldehyde and cyclamenaldehyde amounted to 96%. The optimum amount was found to be 1.0–1.3 equivalents of cobalt carbonyl." @default.
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- W2005228774 date "1973-11-01" @default.
- W2005228774 modified "2023-10-15" @default.
- W2005228774 title "The Selective Hydrogenation of α-Methylcinnamaldehydes Catalyzed by Cobalt Carbonyl in the Presence of Amines" @default.
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- W2005228774 doi "https://doi.org/10.1246/bcsj.46.3562" @default.
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