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- W2005228923 abstract "Racemic diaminosugars were easily obtained by a regio- and stereoselective three-step synthetis. In the first step, regiospecific hetero-Diels-Alder cycloadditions between 1,2-dihydropyridines 1a and 10 and nitrosobenzene led to the bicyclic compounds 2a and 11, respectively, cis-Glycol formation starting from these latter adducts, followed by hydrogenolysis of the NO bond and by exhaustive acetylation of the OH-groups, led to the diaminolyxose 5, the diaminomannose 14 and the diaminoallose 15. When starting from benzyl 1,2-dihydropyridine-1-carboxylate (1b) and using the same reaction sequence, the racemic piperidine derivative 8 was obtained." @default.
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- W2005228923 date "1985-02-13" @default.
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- W2005228923 title "Syntheses of Racemic Diaminosugar Derivatives Starting from 1,2-Dihydropyridines and from Nitrosobenzene" @default.
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- W2005228923 doi "https://doi.org/10.1002/hlca.19850680112" @default.
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