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• W2005229258 endingPage "422" @default.
• W2005229258 startingPage "407" @default.
• W2005229258 abstract "When aqueous solutions of polycations and polyanions are mixed, polyelectrolyte complexes form. These are usually insoluble in water, so that they separate out as a new concentrated polymer phase, called a complex coacervate. The behavior of these complexes is reviewed, with emphasis on new measurements that shed light on their structural and mechanical properties, such as cohesive energy, interfacial tension, and viscoelasticity. It turns out that stoichiometric complexes can be considered in many respects as pseudo-neutral, weakly hydrophobic polymers, which are insoluble in water, but become progressively more soluble as salt is added. In fact, the solubility-enhancing effect of salt is quite analogous to that of temperature for polymers in apolar solvents. Since two-phase systems can be prepared in colloidal form, we also discuss several kinds of colloids or ‘microphases’ that can arise due to polyelectrolyte complexation, such as thin films, ‘zipper’ brushes, micelles, and micellar networks. A characteristic feature of these charge-driven two-phase systems is that two polymeric ingredients are needed, but that some deviation from strict stoichiometry is tolerated. This turns out to nicely explain how and when the layer-by-layer method works, how a ‘leverage rule’ applies to the density of the ‘zipper brush’, and why soluble complexes or micelles appear in a certain window of composition. As variations on the theme, we discuss micelles with metal ions in the core, due to incorporation of supramolecular coordination polyelectrolytes, and micellar networks, which form a new kind of physical gels with unusual properties." @default.
• W2005229258 created "2016-06-24" @default.
• W2005229258 creator A5022792563 @default.
• W2005229258 creator A5074132674 @default.
• W2005229258 creator A5076719382 @default.
• W2005229258 creator A5091764794 @default.
• W2005229258 date "2011-09-01" @default.
• W2005229258 modified "2023-10-10" @default.
• W2005229258 title "Polyelectrolyte complexes: Bulk phases and colloidal systems" @default.
• W2005229258 cites W1560355462 @default.
• W2005229258 cites W1669004436 @default.
• W2005229258 cites W1963897373 @default.
• W2005229258 cites W1965573866 @default.
• W2005229258 cites W1966136237 @default.
• W2005229258 cites W1970396011 @default.
• W2005229258 cites W1973682062 @default.
• W2005229258 cites W1973743903 @default.
• W2005229258 cites W1977175839 @default.
• W2005229258 cites W1979540081 @default.
• W2005229258 cites W1980522922 @default.
• W2005229258 cites W1981116617 @default.
• W2005229258 cites W1982125469 @default.
• W2005229258 cites W1983614617 @default.
• W2005229258 cites W1986202665 @default.
• W2005229258 cites W1987016368 @default.
• W2005229258 cites W1987328734 @default.
• W2005229258 cites W1990615086 @default.
• W2005229258 cites W1990986972 @default.
• W2005229258 cites W1991668940 @default.
• W2005229258 cites W1997864281 @default.
• W2005229258 cites W1998472666 @default.
• W2005229258 cites W1999097650 @default.
• W2005229258 cites W2004835499 @default.
• W2005229258 cites W2008731892 @default.
• W2005229258 cites W2010632420 @default.
• W2005229258 cites W2016963426 @default.
• W2005229258 cites W2017841677 @default.
• W2005229258 cites W2018569753 @default.
• W2005229258 cites W2019102686 @default.
• W2005229258 cites W2019140542 @default.
• W2005229258 cites W2020591453 @default.
• W2005229258 cites W2020889072 @default.
• W2005229258 cites W2022650605 @default.
• W2005229258 cites W2023077713 @default.
• W2005229258 cites W2024051532 @default.
• W2005229258 cites W2026408499 @default.
• W2005229258 cites W2026863404 @default.
• W2005229258 cites W2029851331 @default.
• W2005229258 cites W2031324741 @default.
• W2005229258 cites W2031820392 @default.
• W2005229258 cites W2032472980 @default.
• W2005229258 cites W2034301728 @default.
• W2005229258 cites W2034731253 @default.
• W2005229258 cites W2035775989 @default.
• W2005229258 cites W2035995099 @default.
• W2005229258 cites W2036460780 @default.
• W2005229258 cites W2038994837 @default.
• W2005229258 cites W2040261391 @default.
• W2005229258 cites W2040728588 @default.
• W2005229258 cites W2044153187 @default.
• W2005229258 cites W2045573038 @default.
• W2005229258 cites W2046377044 @default.
• W2005229258 cites W2048410474 @default.
• W2005229258 cites W2049298982 @default.
• W2005229258 cites W2051230189 @default.
• W2005229258 cites W2051624225 @default.
• W2005229258 cites W2051667187 @default.
• W2005229258 cites W2051701671 @default.
• W2005229258 cites W2054898496 @default.
• W2005229258 cites W2056618936 @default.
• W2005229258 cites W2057876748 @default.
• W2005229258 cites W2059298390 @default.
• W2005229258 cites W2059684939 @default.
• W2005229258 cites W2060845774 @default.
• W2005229258 cites W2063173103 @default.
• W2005229258 cites W2064061802 @default.
• W2005229258 cites W2065422398 @default.
• W2005229258 cites W2066996678 @default.
• W2005229258 cites W2067630730 @default.
• W2005229258 cites W2068318214 @default.
• W2005229258 cites W2069812031 @default.
• W2005229258 cites W2070545262 @default.
• W2005229258 cites W2070838947 @default.
• W2005229258 cites W2071149973 @default.
• W2005229258 cites W2073057936 @default.
• W2005229258 cites W2073899913 @default.
• W2005229258 cites W2076770928 @default.
• W2005229258 cites W2077048035 @default.
• W2005229258 cites W2077293962 @default.
• W2005229258 cites W2078430300 @default.
• W2005229258 cites W2080762412 @default.
• W2005229258 cites W2080994059 @default.
• W2005229258 cites W2081496235 @default.
• W2005229258 cites W2082549153 @default.
• W2005229258 cites W2085418279 @default.
• W2005229258 cites W2087278742 @default.
• W2005229258 cites W2087543274 @default.
• W2005229258 cites W2087569661 @default.

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