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- W2005237715 abstract "As the temperature is progressively raised, the alternating copolymer of vinyl acetate and crotonic acid degrades in two main stages: in the first (up to about 270°C), acetic acid is lost through a lactonisation reaction between the dissimilar chain units, accompanied by a parallel reaction involving decarboxylation of some of the crotonic acid groups. At higher temperatures, some further acetic acid loss occurs, but the main degradation products are carbon dioxide, from decomposition of the γ-lactone rings, and chain fragments from the lactonised backbone formed at lower temperatures. A variety of minor volatile products are also formed in the second degradation stage. Unlike poly(vinyl acetate), the copolymer degrades almost without residue by 500°C." @default.
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- W2005237715 date "1994-01-01" @default.
- W2005237715 modified "2023-10-18" @default.
- W2005237715 title "Thermal degradation studies of alternating copolymers. II. The copolymer of vinyl acetate and crotonic acid" @default.
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- W2005237715 doi "https://doi.org/10.1016/0141-3910(94)90146-5" @default.
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