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- W2005245641 abstract "Abstract The single isolobal displacement reaction of (μ3-Se)FeCo2(CO)9 with η5-RC5H4M(CO)3Na can occur in refluxing THF to give single clusters η5-RC5H4(CO)2MCoFe(μ3-Se)(CO)6 (la M = Mo, R = EtO2C; lb M = W, R = MeCO; 1c M = W, R = MeO2C), whereas the functional transformation reaction of 1b with 2, 4-dinitrophenylhydrazine affords its phenylhydrazone derivative η5-2, 4-(NO2)2C6H3NHNC(Me)C5H4(CO)2WCoFe(μ3-Se)(CO)6 (2). More interestingly, the double isolobal displacement reaction of two molecules of (μ3-Se)FeCo2(CO)9 with [μ5-C5H4C(O)CH2M(CO)3Na]2 takes place in THF at reflux, giving double clusters [μ5-C5H4C(O)CH2]2[(CO)2MCoFe(μ3-Se)(CO)6]2 (3a M = Mo; 3b M = W), whereas 3a reacts with Cp2Ni in refluxing THF to afford both single and double isolobal displacement products [μ5-C5H4C(O)CH2]2[(CO)2MoNiFe(μ3-Se)(CO)3Cp][(CO)2MoCoFe(μ3-Se)(CO)6] (4) and [μ5-C5H4C(O)CH2]2[(CO)2MoNiFe(μ3-Se)(CO)3Cp]2 (5). All products were characterized by-analysis and spectroscopy, as well as for 1c by an X-ray diffraction analysis." @default.
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- W2005245641 title "SYNTHESIS OF SINGLE AND DOUBLE μ3-Se-CONTAINING TETRAHEDRAL MCoFe(μ<sub>3</sub>-Se) AND MNiFe(μ<sub>3</sub>-Se) (M = Mo, W) CLUSTERS <i>VIA</i> ISOLOBAL AND FUNCTIONAL REACTIONS. CRYSTAL AND MOLECULAR STRUCTURE OF η<sup>5</sup>-MeO<sub>2</sub>CC<sub>5</sub>H<sub>4</sub>(CO)<sub>2</sub>WCoFe(μ<sub>3</sub>-Se)(CO)<sub>6</sub>" @default.
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- W2005245641 doi "https://doi.org/10.1080/00958979908023069" @default.
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