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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005246445> ?p ?o ?g. }

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• W2005246445 abstract "During efforts to stabilize metal oxide bound chromophores for photoelectrochemical applications, a novel photochemical reaction has been discovered. In the reaction, the bisphosphonate functional groups −C(PO3H2)2(OH) in the metal complex [Ru(bpy)2(4,4′-(C(OH)(PO3H2)2bpy)]2+ are converted into −COOH and H3PO4. The reaction occurs by sensitized formation of 1O2 by the lowest metal-to-ligand charge transfer excited state(s) of [Ru(bpy)2(4,4′-(C(PO3H2)2(OH))2(bpy))]2+* followed by 1O2 oxidation of the bisphosphonate substituent. A related reaction occurs for the bisphosphonate-based drug, risedronic acid, in the presence of O2, light, and a singlet oxygen sensitizer ([Ru(bpy)3]2+ or Rose Bengal)." @default.
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• W2005246445 date "2012-10-08" @default.
• W2005246445 modified "2023-10-17" @default.
• W2005246445 title "Sensitized Photodecomposition of Organic Bisphosphonates By Singlet Oxygen" @default.
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• W2005246445 doi "https://doi.org/10.1021/ja307987g" @default.
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