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- W2005249123 abstract "Proton conducting membranes have been prepared using sulfonated poly[bis(phenoxy)phosphazene] (s-BPP) trapped in a cross-linked interpenetrating hydrophilic network of hexa(vinyloxyethoxyethoxy)cyclotriphosphazene (CVEEP). Membranes with good mechanical and thermal stabilities were obtained exhibiting high ion exchange capacities in the range of 1.62–1.79 mmol/g. The proton conductivity was measured as a function of water partial pressure in nitrogen (0 mbar to 25 mbar) in the temperature range 25 °C to 75 °C. At 25 mbar water partial pressure and 75 °C, a conductivity of 2.2 × 10− 4 S/cm was obtained for s-BPP with a network made of 50 wt.% CVEEP. After immersion in water, the conductivity increased up to 0.013 S/cm at 25 °C. The hydrophilic nature of the CVEEP network stabilizes the water content and enhances the proton conductivity at elevated temperatures." @default.
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- W2005249123 date "2006-10-31" @default.
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- W2005249123 title "Proton conducting membranes from sulfonated poly[bis(phenoxy)phosphazenes] with an interpenetrating hydrophilic network" @default.
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- W2005249123 doi "https://doi.org/10.1016/j.ssi.2006.05.007" @default.
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