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- W2005271710 abstract "We demonstrate the versatility of polymers made by reversible addition–fragmentation chain transfer (RAFT) to be cyclized in one-pot using the thiol–ene reaction. Hexylamine was used to convert the RAFT end-group to a free thiol which rapidly reacted with the acrylate on the other chain-end of the polymer to form a cyclic polymer. This procedure allowed a wide range of polymers (polystyrene, poly(tert-butyl acrylate), poly(N-isopropylacrylamide) and poly(N,N-dimethylacrylamide)) to be cyclized with close to 80% cyclic formation. These cyclic polymers all contained a reactive alkyne functional group. Attempts to use the thio–bromo reaction to cyclize polystyrene were not as successful as the thiol–ene cyclization reaction, producing less than 25% cyclic." @default.
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- W2005271710 date "2013-01-01" @default.
- W2005271710 modified "2023-10-18" @default.
- W2005271710 title "Synthesis of alkyne functional cyclic polymers by one-pot thiol–ene cyclization" @default.
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- W2005271710 doi "https://doi.org/10.1039/c3py21109f" @default.
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