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• W2005280557 abstract "E-mail: hongjh@chosun.ac.krReceived June 2, 2011, Accepted June 29, 2011Novel 5'-norcarbocyclic adenine and guanine phosphonic acid analogues with 6'-electronegative moiety suchas unsaturated C-C bond were designed and synthesized from commercially available 2-methylene-propane-1,3-diol (4). Regioselective Mitsunobu reaction successfully proceeded from an allylic functional group (±)-12b at low reaction temperature in polar cosolvent (DMF/1,4-dioxane) to give purine phosphonate analogues(±)-13 and (±)-20. The purine nucleoside phosphonate and phosphonic acid analogues were subjected toantiviral screening against HIV-1. Guanine analogue (±)-23 shows significant anti-HIV activity in PBM celllines (EC" @default.
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• W2005280557 date "2011-08-20" @default.
• W2005280557 modified "2023-09-22" @default.
• W2005280557 title "Racemic Synthesis of Novel 6'-Methylene-5'-norcarbocyclic Purine Phosphonic Acid Analogues via Mitsunobu Reaction" @default.
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• W2005280557 doi "https://doi.org/10.5012/bkcs.2011.32.8.2689" @default.
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