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- W2005284073 abstract "Reaction of the hydroxyamine 7-chloro-4-(hydroxyamino)quinoline with the triosmium cluster Os3(CO)10(NCMe)2 gave the complex (μ-H)Os3(CO)10(μ2-η1-O-C9H6N2Cl) (3), in which a new mode of μ2-η1-O-oximato ligand bridged two osmium centers by an oxygen atom. This complex was slowly converted to (μ-H)Os3(CO)10(μ2-η2-ON-C9H6NCl) (4), where an aromatic C−H moiety in the μ2-η2-ON-oximatoquinoline group formed an unusual short intramolecular C−H···O−N hydrogen bond and an intermolecular C−H···OC hydrogen bond simultaneously. The formation of the intramolecular hydrogen bond may provide a stabilization effect for the generation of the η2-ON complex 4 and a driving force for the transformation of 3 to 4." @default.
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- W2005284073 date "2000-01-14" @default.
- W2005284073 modified "2023-10-16" @default.
- W2005284073 title "New Coordination Modes of an Oxime Ligand in a Triosmium Cluster. Stabilization by Intra- and Intermolecular C−H···O Hydrogen Bonds" @default.
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- W2005284073 doi "https://doi.org/10.1021/om990441v" @default.
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