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- W2005291011 abstract "The stereoselective introduction of the brassinolide side-chain, having a (20S,22R,23R,24S)-22,23-diol functionality, was examined. The catalytic reduction of (20S,22R,24Z)-6β-methoxy-23-oxo-3α,5-cyclo-5α-stigmast-24(28)-eno-29,22-lactone (11), derived from the 20-carbaldehyde (7) and 3-isopropyl-2-lithiofuran in three steps, afforded (20S,22R,23R,24S)-22-hydroxy-6β-methoxy-3α,5-cyclo-5α-stigmastano-29,23-lactone (14), an important intermediate for the stereoselective synthesis of brassinolide." @default.
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- W2005291011 date "1988-01-01" @default.
- W2005291011 modified "2023-10-09" @default.
- W2005291011 title "Stereocontrolled synthesis of the brassinolide side-chain: formal synthesis of brassinolide" @default.
- W2005291011 doi "https://doi.org/10.1039/p19880001503" @default.
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