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- W2005305859 abstract "Electronic transitions of the triplet chain C5H− anion were studied using detachment spectroscopy. The system detected in the vicinity of the electron detachment threshold is assigned to the b3A ← a3A transition with a dipole bound state (DBS) character. The second system measured by autodetachment spectroscopy is attributed to the c3A ← a3A Feshbach electronic transition. Negative anharmonicity of the vibrational progression built upon the low frequency CCC in-plane bending mode ν 12 is observed in both DBS and Feshbach states. This indicates a barrier to linearity on the potential energy surface in both excited states. The triplet chain C5H− anion exhibits similar electronic properties to C3H−. Renner-Teller and vibronic effects between the 3A DBS and Feshbach states are inferred and may explain the stabilisation of the DBS. This interaction is weaker in C5H− than C3H− leading to smaller barrier heights on the potential energy surface." @default.
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- W2005305859 date "2010-04-10" @default.
- W2005305859 modified "2023-09-27" @default.
- W2005305859 title "Electronic transitions of the C5H−anion" @default.
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- W2005305859 doi "https://doi.org/10.1080/00268970903501691" @default.
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