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- W2005307557 abstract "Abstract The electrochemical reduction of allyl halides is strongly catalysed when it is carried out by cathodically generating and continuously recycling the nickel(0) complex promoter |Ni(PPh 3 ) 4 |(PPh 3 = triphenylphosphine). This species undergoes oxidative addition by allyl halides leading to π -bonded organometallic nickel(I) derivatives, the metal-carbon bond of which is cleaved by means of an electrochemical reduction providing 1,5-hexadiene as the coupling product and renewing the nickel(0) promoter, thus allowing an electrocatalytic cycle to be completed. Voltammetric, coulometric and gas-chromatographic data are presented and analysed. To account for the catalytic action of the nickel(0) complex, a mechanistic scheme is proposed which is consistent with the kinetic data obtained by studying the chemical reaction coupled with charge transfers by means of the voltammetric technique." @default.
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- W2005307557 date "1984-01-01" @default.
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- W2005307557 title "An electroanalytical investigation on the electrocatalysed coupling of allyl halides promoted by the nickel-triphenylphosphine system" @default.
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- W2005307557 doi "https://doi.org/10.1016/s0022-0728(84)80129-1" @default.
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