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- W2005308998 abstract "Oligomerization of isobutene has been investigated using several cation exchange resins in order to produce triisobutenes that are useful feedstock for heavy alkylates and neo-acids. Trimers selectivity increases with increasing isobutene conversion. High isobutene conversion is obtained at high temperature and low space velocity by using macroporous cation exchange resins that have high concentration of sulfonic acid groups. Under selected conditions (viz., isobutene WHSV: 10 h−1; temperature: 70 °C; catalyst: Amberlyst-35), the isobutene is quantitatively oligomerized with higher than or equal to 70% selectivity for trimers. The wet resin catalysts containing water or ethanol are very stable for the oligomerization up to about 70 h contrary to the gradual decrease in the conversion with dehydrated catalysts." @default.
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- W2005308998 date "2006-12-01" @default.
- W2005308998 modified "2023-09-24" @default.
- W2005308998 title "Trimerization of isobutene over cation exchange resins: Effect of physical properties of the resins and reaction conditions" @default.
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- W2005308998 doi "https://doi.org/10.1016/j.molcata.2006.07.026" @default.
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