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• W2005319158 abstract "This work describes the application of a tertiary amine containing material, namely N,N-dimethylpropylamine-grafted pore-expanded mesoporous silica (TER-PE-MCM-41) for selective adsorption of SO2. The amine loading was 3.26 mmol/g. In the presence of 1% SO2/N2, the SO2 adsorption capacity was 2.19 mmol/g under dry condition at 23 °C, corresponding to a SO2/N ratio of 0.67. The adsorption took place presumably via formation of a charge transfer complex. The presence of water vapor had a positive effect on the adsorption capacity of SO2, which increased threefold in the presence of 32% relative humidity. The SO2-saturated adsorbents in both dry and humid conditions were fully regenerated at 130 °C under N2. The SO2 working capacity remained almost unchanged in consecutive adsorption/regeneration cycles. No measurable CO2 adsorption over TER-PE-MCM-41 was detected, and the presence of CO2 did not cause any adverse effect on SO2 uptake under dry or humid conditions." @default.
• W2005319158 created "2016-06-24" @default.
• W2005319158 creator A5051756347 @default.
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• W2005319158 date "2014-03-01" @default.
• W2005319158 modified "2023-10-18" @default.
• W2005319158 title "Selective removal of SO2 over tertiary amine-containing materials" @default.
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• W2005319158 doi "https://doi.org/10.1016/j.cej.2013.11.002" @default.
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