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- W2005322568 abstract "The decomposition of 0.25%, 0.50%, and 1.00% NF3 in argon was studied in a reflected shock wave. In these dilute mixtures the unimolecular decomposition pathway can be studied independently of other modes of decomposition. The temperature range of the study was 1500–2400 °K and the total pressure range was 0.8–60 atm. The total gas concentration behind the reflected shock ranged from 5×10−6 to 3.6×10−4 mol/cc. Kinetic measurements were made by following the decay of emission of the ν3+ν1 combination band of NF3 at 5.18 μ. The unimolecular rate constants of the Lindemann mechanism were obtained from the emission decay data and were converted to second order rate constants by dividing by the total gas concentration. The Arrhenius parameters calculated by a least squares analysis of the second order rate constants are given as k=1014.7 exp(−56 300/RT) cc/mol sec. The activation energy for the reaction is very close to the first N–F bond energy of 57 kcal/mol. Calculations using the Slater integral were in good agreement with experimental results. The results suggest that under the reported conditions vibrational equilibrium is not maintained during reaction." @default.
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- W2005322568 date "1975-10-15" @default.
- W2005322568 modified "2023-10-14" @default.
- W2005322568 title "Shock tube decomposition of dilute mixtures of nitrogen trifluoride in argon" @default.
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- W2005322568 doi "https://doi.org/10.1063/1.431750" @default.
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