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• W2005353313 abstract "XPS line decomposition of carbon residues on Pt-black and EUROPT-1 reveal the presence of a graphitic, hydrocarbon polymer and oxidized carbon overlayers on both catalysts. Usual regeneration pretreatment with oxygen and hydrogen at reaction temperatures (ca. 600 K) does not remove all carbon from Pt-black or EUROPT-1 but an O2 treatment of EUROPT-1 at 673 K removes most of the carbon. A ‘coke sensitivity’ is suggested as an additional factor influencing the ‘selectivity’ (the 2-methylpentane/n-hexane (2MP/nH) ratio) of ring opening of methylcyclopentane, the absence of oxidized carbonaceous entities being necessary to produce low 2MP/nH ratios." @default.
• W2005353313 created "2016-06-24" @default.
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• W2005353313 date "1994-11-01" @default.
• W2005353313 modified "2023-10-18" @default.
• W2005353313 title "XPS of carbon on Pt-black and EUROPT-1. Is methylcyclopentane ring opening a ‘coke sensitive’ reaction?" @default.
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• W2005353313 doi "https://doi.org/10.1016/s0304-5102(94)87044-6" @default.
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