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- W2005353668 abstract "Free energies Δgx, enthalpies Δhx and entropies TΔsx of mixing were calculated for eight polymer-polymer systems. It was shown that the polymer compositions studied, in respect of the shape of the curve showing the concentration dependence Δgx, may be classified in three groups: stable, metastable and unstable. For a stable cellulose nitrate-polyvinylacetate system a reduction in entropy was observed during mixing, which may be due to ordering of elements of the system. For metastable systems thermodynamic functions of mixing Δhx and TΔsx are positive in one range of composition and negative in the other. An unstable polymethylmethacrylate-polybutylmethacrylate system undergoes endothermic mixing over the entire range of composition and the free energy varies positively and entropy of mixing increases in this case." @default.
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- W2005353668 date "1975-01-01" @default.
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- W2005353668 title "Thermodynamics of mixing polymers" @default.
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- W2005353668 doi "https://doi.org/10.1016/0032-3950(75)90350-0" @default.
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