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- W2005367689 abstract "Kinetic and spectral studies were performed on solutions of trans-Copy4(H2O)23+ ion in aqueous acidic chloride solutions at 30 and 40 °C. The simplest interpretation of the data at the experimental conditions is in terms of two consecutive first-order reactions. The fast reaction is dependent on chloride ion and exhibits a non-linear inverse dependence on hydrogen ion. Our analysis of the absorbance-time data suggests that the title complex undergoes an acid dissociation equilibrium and that the deprotonated form loses a bound pyridine. This is associated with substitution by water and chloride as parallel steps. A slower reaction follows and is found to be inversely dependent on hydrogen ion, but the chloride ion dependence is not simple. We associate this step with the decomposition and reduction of Co(py)3(H2O)33+ and Co(py)3(H2O)2Cl2+ as well as their corresponding conjugate bases to ultimately form CO2+(aq). Mechanisms for the fast and slow steps are presented and mechanistic constants associated from these are estimated." @default.
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- W2005367689 date "1955-10-01" @default.
- W2005367689 modified "2023-09-23" @default.
- W2005367689 title "Mechanism of basic hydrolysis of cobalt(III) complexes" @default.
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- W2005367689 doi "https://doi.org/10.1016/0022-1902(55)80042-5" @default.
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