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• W2005371288 abstract "The preparation of β-SiC/MC (M = Ti, Nb, and Ta) nanocomposite ceramics by the pyrolysis under an inert atmosphere of precursors consisting in interpenetrating networks of poly[(dimethylsilylene)diacetylene], 1, and polymeric metal oxide is described. The precursors are obtained by in-situ precipitation of the desired metal alkoxide into the organosilicon polymeric matrix. The precursor-to-ceramic conversion involved two critical transformations: (i) the thermal cross-linking of 1 and (ii) the carbothermal reduction of the oxide by the free carbon resulting from the degradation of 1. At 1400 °C, the pure carbides are obtained as nanometer-sized highly crystalline powders. Analyses have shown that both β-SiC and the other metal carbide are present simultaneously in each ceramic particle as discrete phases. All of these results show that we are faced with materials that can be described as nanocomposite ceramics with interpenetrating networks." @default.
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• W2005371288 date "2000-03-01" @default.
• W2005371288 modified "2023-10-16" @default.
• W2005371288 title "From Preceramic Polymers with Interpenetrating Networks to SiC/MC Nanocomposites" @default.
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• W2005371288 doi "https://doi.org/10.1021/cm991140e" @default.
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