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- W2005380937 abstract "Single crystals of CsPr 2 (CH 3 COO) 7 were obtained from an acetic acid solution of Pr(CH 3 COO) 3 • H 2 O and Cs 2 CO 3 in a molar ratio of 4:1 at 120°C. It crystallizes in the triclinic system, PĪ (no. 2), Z = 2, a = 1028.1(5), b = 1034.6(5), c = 1199.4(6) pm, α = 84.82(2), β = 67.07(3), γ = 76.01(2)°, V m = 343.3(3) cm 3 /mol, R = 0.031, R w = 0.027. The crystal structure contains infinite chains, 1 ∞ [Pr 2 (CH 3 COO) 6 ], running along the [110] direction. The chains are built up by bridging acetate ions coordinated to two crystallographically different Pr 3+ ions which are both surrounded by 9 oxygen ligands. These chains are linked by “intercalated” Cs(CH 3 COO) to layers parallel (100). Cs + has contacts to oxygen atoms of neighbouring layers, such that a three-dimensional network is formed." @default.
- W2005380937 created "2016-06-24" @default.
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- W2005380937 date "1993-07-01" @default.
- W2005380937 modified "2023-10-14" @default.
- W2005380937 title "CsPr<sub>2</sub>(CH<sub>3</sub>COO)<sub>7</sub>, ein caesiumarmes wasserfreies ternäres Caesium-Praseodym-Acetat / CsPr<sub>2</sub>(CH<sub>3</sub>COO)<sub>7</sub>, a Cesium Poor Anhydrous Ternary Cesium Praseodymium(III) Acetate" @default.
- W2005380937 doi "https://doi.org/10.1515/znb-1993-0705" @default.
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