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- W2005391657 abstract "The thermodynamic parameters for the formation of 1:1 metal-to-ligand complexes of 1,4 dinitrilobutane, N,N,N′,N′ :tetraacetate (TMEDTA) with lanthanide cations have been determined at 25 °C and 0.50 M (NaClO4) ionic strength. The enthalpy of complexation is endothermic so the stability of the complexes is due to the large, positive entropies. Arguments are presented for much weaker lanthanide-nitrogen interactions in the LnTMEDTA complex than in the LnEDTA, presumably due to the larger N-Ln-N chelate ring of the former." @default.
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- W2005391657 modified "2023-09-26" @default.
- W2005391657 title "Thermodynamics of lanthanide TMEDTA complexation" @default.
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- W2005391657 doi "https://doi.org/10.1016/s0020-1693(00)84548-x" @default.
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