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- W2005394083 abstract "Abstract Octalactin A, an antitumor agent containing an eight‐membered lactone moiety, has been stereoselectively prepared by means of enantioselective aldol reactions of selected silyl enolates with achiral aldehydes, promoted by a chiral Sn II complex. The medium‐sized lactone part was effectively constructed by way of a new and rapid mixed‐anhydride lactonization using 2‐methyl‐6‐nitrobenzoic anhydride (MNBA) with a catalytic amount of 4‐(dimethylamino)pyridine (DMAP) or 4‐(dimethylamino)pyridine 1‐oxide (DMAPO). The use of only 5 mol % of DMAP or 2 mol % of DMAPO rapidly promoted formation of the medium‐sized ring of the octalactin, demonstrating the remarkable efficiency of the new lactonization protocol." @default.
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- W2005394083 date "2005-10-26" @default.
- W2005394083 modified "2023-10-11" @default.
- W2005394083 title "Enantioselective Total Synthesis of Octalactin A Using Asymmetric Aldol Reactions and a Rapid Lactonization To Form a Medium-Sized Ring" @default.
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- W2005394083 cites W1981131165 @default.
- W2005394083 cites W1981686319 @default.
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- W2005394083 doi "https://doi.org/10.1002/chem.200500417" @default.
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