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- W2005394894 abstract "Abstract The energy separation of the first excited spin-orbit States Γ 3g , Γ 4g from the Γ 5g ground state, in the orbital 5 T 2g triplet state of Fe 2+ in KMgF 3 , has been estimated from temperature dependence measurements on the 7860 cm -1 zero-phonon-line (ZPL) transition from Γ 5g to the orbital 5 E g doublet state. Using a simplified crystal field energy level model, we find the Γ 5g Γ 3g , Γ 4g separation to be ∼30 cm -1 , indicating that the vibronic Jahn-Teller coupling is considerably stronger in KMgF 3 :Fe 2+ than in MgO:Fe 2+ . Far infrared absorption data on KMgF 3 :Fe 2+ in magnetic fields up to 6T, are found to be consistent with this interpretation." @default.
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- W2005394894 date "1977-06-01" @default.
- W2005394894 modified "2023-09-26" @default.
- W2005394894 title "Indirect measurements of the Jahn-Teller quenched spin-orbit splitting in the 5T2g-state of KMgF3:Fe2+" @default.
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- W2005394894 doi "https://doi.org/10.1016/0038-1098(77)90781-5" @default.
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