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• W2005404009 abstract "Structures of NASICON glasses of the general formula AB2(PO4)3, where A = Li, Na or K and B = Fe, Ga, Ti, V or Nb, have been investigated using vibrational (IR and Raman) spectroscopies. Phosphate species appear to establish an equilibrium via a disproportionation reaction involving a dynamical bond-switching mechanism where both charge and bonds are conserved. B ions in the system acquire different coordinations to oxygens. Alkali ions cause absorptions due to cage vibrations. All the observed spectroscopic features are consistent with speciation involving disproportionation reactions." @default.
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• W2005404009 date "2001-10-01" @default.
• W2005404009 modified "2023-09-27" @default.
• W2005404009 title "Infrared and Raman spectroscopic studies of glasses with NASICON-type chemistry" @default.
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• W2005404009 doi "https://doi.org/10.1007/bf02708786" @default.
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