FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005405719> ?p ?o ?g. }

• W2005405719 endingPage "5328" @default.
• W2005405719 startingPage "5316" @default.
• W2005405719 abstract "Gas phase spectroscopic studies of copper trimer are reported. A band system in the 5430–5225 Å region has been assigned to Cu3 and has been studied by resonant two-photon ionization spectroscopy, spectroscopy by depletion through predissociation, and by radiation repopulation of excited vibrational states in a cold supersonic molecular beam. The spectrum fits well to a 2E″←2E′ transition of a D3h molecule with both states undergoing Jahn–Teller distortions. In this interpretation, the excited state is well described by a weak Jahn–Teller effect, stabilizing the molecule at a configuration in which one Cu–Cu bond length differs from the others by 0.03 Å, with a Jahn–Teller stabilization energy of 9 cm−1. The ground electronic state corresponds to a deep Jahn–Teller situation with the lowest vibronic levels trapped in the distorted configuration. The spectra indicate the tunneling splitting of the lowest vibrational levels in the ground state is 12±7 cm−1. These assignments are based on measured vibrational band positions and may not be unique. Definitive determination of the copper trimer structure will require analysis of rotational fine structure which was unresolved with the laser sources available in this study." @default.
• W2005405719 created "2016-06-24" @default.
• W2005405719 creator A5005334941 @default.
• W2005405719 creator A5015746014 @default.
• W2005405719 creator A5039967104 @default.
• W2005405719 creator A5083928925 @default.
• W2005405719 date "1983-12-01" @default.
• W2005405719 modified "2023-09-27" @default.
• W2005405719 title "Spectroscopic studies of the jet-cooled copper trimer" @default.
• W2005405719 cites W1651078840 @default.
• W2005405719 cites W1963987339 @default.
• W2005405719 cites W1967697423 @default.
• W2005405719 cites W1971058782 @default.
• W2005405719 cites W1977517308 @default.
• W2005405719 cites W1979297697 @default.
• W2005405719 cites W1985646140 @default.
• W2005405719 cites W1988783144 @default.
• W2005405719 cites W1996583969 @default.
• W2005405719 cites W2001343203 @default.
• W2005405719 cites W2010365447 @default.
• W2005405719 cites W2035709224 @default.
• W2005405719 cites W2037290187 @default.
• W2005405719 cites W2037297682 @default.
• W2005405719 cites W2041212360 @default.
• W2005405719 cites W2045643951 @default.
• W2005405719 cites W2055007845 @default.
• W2005405719 cites W2055601718 @default.
• W2005405719 cites W2057523404 @default.
• W2005405719 cites W2070645483 @default.
• W2005405719 cites W2089667532 @default.
• W2005405719 cites W2093403765 @default.
• W2005405719 cites W2094461150 @default.
• W2005405719 cites W2121672200 @default.
• W2005405719 cites W2131650268 @default.
• W2005405719 cites W2146406469 @default.
• W2005405719 cites W2154324764 @default.
• W2005405719 cites W2506154754 @default.
• W2005405719 cites W2951185351 @default.
• W2005405719 cites W3005080520 @default.
• W2005405719 cites W4239780738 @default.
• W2005405719 doi "https://doi.org/10.1063/1.445694" @default.
• W2005405719 hasPublicationYear "1983" @default.
• W2005405719 type Work @default.
• W2005405719 sameAs 2005405719 @default.
• W2005405719 citedByCount "224" @default.
• W2005405719 countsByYear W20054057192012 @default.
• W2005405719 countsByYear W20054057192014 @default.
• W2005405719 countsByYear W20054057192015 @default.
• W2005405719 countsByYear W20054057192016 @default.
• W2005405719 countsByYear W20054057192019 @default.
• W2005405719 countsByYear W20054057192020 @default.
• W2005405719 countsByYear W20054057192021 @default.
• W2005405719 countsByYear W20054057192023 @default.
• W2005405719 crossrefType "journal-article" @default.
• W2005405719 hasAuthorship W2005405719A5005334941 @default.
• W2005405719 hasAuthorship W2005405719A5015746014 @default.
• W2005405719 hasAuthorship W2005405719A5039967104 @default.
• W2005405719 hasAuthorship W2005405719A5083928925 @default.
• W2005405719 hasConcept C121332964 @default.
• W2005405719 hasConcept C145148216 @default.
• W2005405719 hasConcept C155860418 @default.
• W2005405719 hasConcept C178790620 @default.
• W2005405719 hasConcept C181500209 @default.
• W2005405719 hasConcept C184779094 @default.
• W2005405719 hasConcept C185592680 @default.
• W2005405719 hasConcept C198291218 @default.
• W2005405719 hasConcept C2776403692 @default.
• W2005405719 hasConcept C2779546866 @default.
• W2005405719 hasConcept C32891209 @default.
• W2005405719 hasConcept C32909587 @default.
• W2005405719 hasConcept C41999313 @default.
• W2005405719 hasConcept C62520636 @default.
• W2005405719 hasConcept C69523127 @default.
• W2005405719 hasConcept C83981384 @default.
• W2005405719 hasConceptScore W2005405719C121332964 @default.
• W2005405719 hasConceptScore W2005405719C145148216 @default.
• W2005405719 hasConceptScore W2005405719C155860418 @default.
• W2005405719 hasConceptScore W2005405719C178790620 @default.
• W2005405719 hasConceptScore W2005405719C181500209 @default.
• W2005405719 hasConceptScore W2005405719C184779094 @default.
• W2005405719 hasConceptScore W2005405719C185592680 @default.
• W2005405719 hasConceptScore W2005405719C198291218 @default.
• W2005405719 hasConceptScore W2005405719C2776403692 @default.
• W2005405719 hasConceptScore W2005405719C2779546866 @default.
• W2005405719 hasConceptScore W2005405719C32891209 @default.
• W2005405719 hasConceptScore W2005405719C32909587 @default.
• W2005405719 hasConceptScore W2005405719C41999313 @default.
• W2005405719 hasConceptScore W2005405719C62520636 @default.
• W2005405719 hasConceptScore W2005405719C69523127 @default.
• W2005405719 hasConceptScore W2005405719C83981384 @default.
• W2005405719 hasIssue "11" @default.
• W2005405719 hasLocation W20054057191 @default.
• W2005405719 hasOpenAccess W2005405719 @default.
• W2005405719 hasPrimaryLocation W20054057191 @default.
• W2005405719 hasRelatedWork W1017473139 @default.
• W2005405719 hasRelatedWork W1484313975 @default.
• W2005405719 hasRelatedWork W1985201143 @default.
• W2005405719 hasRelatedWork W1996469061 @default.

• next