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- W2005422017 abstract "The thermal decomposition of SO2 and of the primary dissociation product SO have been studied in shock waves by the uv absorption technique. The controversy about SO2 dissociation data from uv absorption signals was resolved and attributed to the extensive overlap of SO2 and SO uv absorption spectra. The derived rate coefficients are k1/[Ar] = 1015.6 exp(-420 kJmol−1/RT) cm3mol−1 s−1 (temperature range 3000–5000 K) for SO2 dissociation, and k3/[Ar] = 1014.6 exp(-448 kJmol−1/RT) cm3 mol−1 s−1 (temperature range 4000–6000 K) for SO dissociation. Anomalously high values of the apparent collision efficiencies βc in SO2 dissociation are attributed to marked contributions from excited electronic states." @default.
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- W2005422017 date "1984-12-01" @default.
- W2005422017 modified "2023-09-23" @default.
- W2005422017 title "UV absorption study of the dissociation of SO2 and SO in shock waves" @default.
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- W2005422017 doi "https://doi.org/10.1002/kin.550161207" @default.
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