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- W2005433281 abstract "Partial substitution of oxygen by fluorine in TlBa2CuO5 has been achieved by heating Tl2O3, BaO2, BaO and CuO under one kbar external pressure using TlF as a source for fluorine. A single phase region exists for 0.1 ≤ x ≤ 0.5 and the X-ray powder diffraction data indicated a tetragonal structure (space group: P4/mmm) for all the compounds. The in-plane Cu-O distance calculated from the a-lattice parameter showed a systematic increase as x was varied from 0.1 to 0.5. This due to an increase in the formal oxidation state of copper as F1− substitutes for O2− in the 1201-type structure. The c-lattice parameter also showed a slight increase, as the fluorine content in the reaction mixture is increased. Superconductivity is observed for x values within the range 0.1 to 0.6 with transition temperatures in the range 35–75 K." @default.
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- W2005433281 date "1994-02-01" @default.
- W2005433281 modified "2023-09-25" @default.
- W2005433281 title "Stabilization of superconducting phases in thallium-barium-copper oxide system by fluorine substitution [TlBa2CuO5−xFx]" @default.
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- W2005433281 doi "https://doi.org/10.1016/0025-5408(94)90131-7" @default.
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