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- W2005444158 abstract "Upon irradiation, pyrene reacts with cyanide to give 1-cyanopyrene and with amide to give 1-aminopyrene. With oxygen nucleophiles no reaction takes place. Irradiation of pyrene in the presence of diethyl malonate anion yields 4,5,9,10-tetrahydropyrene in high yield, probably via initial electron transfer to excited pyrene. 1-Fluoropyrene can be photosubstituted with oxygen nucleophiles, leading to 1-hydroxy- and 1-methoxy-pyrene, in contrast to 1-chloro- and 1-bromopyrene, which are converted into a mixture of pyrene and 4,5-dihydropyrene upon irradiation." @default.
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- W2005444158 date "2010-09-02" @default.
- W2005444158 modified "2023-10-12" @default.
- W2005444158 title "Photosubstitution and photoreduction of pyrene and 1-halopyrenes" @default.
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- W2005444158 doi "https://doi.org/10.1002/recl.19831020407" @default.
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