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- W2005450140 abstract "Polycrystalline samples of quaternary compounds I2·Mn·IV·VI4, withI = Cu, Ag, IV = Si, Ge, SnandVi = Se, Te, were prepared from the elements using the melt and anneal technique. The majority of these compounds can take more than one structure, depending upon heat treatment, with subcell symmetry of orthorhombic, tetragonal or cubic form, so that a total of 19 phases could be investigated. Because of this behaviour, in some cases preparation involved quenching of a high-temperature phase to a quasistble state at room temperature. For each sample, measurements of magnetic susceptibility χ were made as a function of temperature in the range 4–250 using SQUID magnetometer. The resulting data indicated that seven of these phases were antiferromagnetic while the other 12 showed ferrimagnetic behaviour. A value for the Néel temperature TN was obtained in every case, but because of the presence of small amounts of other phases in some of the quenched samples, values of other parameters such as the Curie-Weiss Θa, etc. could be obtained in only 11 cases. It was found that when TN and Θa were plotted against the effective lattice parameter ae, the phases were divided into five sets, each set being characterized by a particular crystal structure and magnetic behaviour and showing a linear variation of these magnetic parameters with ae." @default.
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- W2005450140 date "1993-01-01" @default.
- W2005450140 modified "2023-10-04" @default.
- W2005450140 title "Magnetic behaviour of some I2·Mn·IV·VI4 compounds" @default.
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- W2005450140 doi "https://doi.org/10.1016/0304-8853(93)90165-x" @default.
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