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- W2005461132 abstract "High-temperature X-ray analyses have been performed to study the relation between the superconducting transition and the responsible phase. It was found that the superconducting orthorhombic phase forms by partly substituting Ca2+ for Y3+ only under very restricted conditions of temperature and partial oxygen pressure. Structural phase instabilities occurring in air near 340 °C and 550 °C can be understood by a change of oxidation states of Cu(I) from Cu+ to Cu2+ and Pb from Pb2+ to Pb4+. It is strongly suggested that ordering of oxygen atoms in the PbOCuOεPbO layers plays an important role for the formation of the superconducting state in the orthorhombic structure." @default.
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- W2005461132 date "1989-12-01" @default.
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- W2005461132 title "High temperature structural instability of the high-T c superconductor Pb 2 Sr 2 Y 1-x Ca x Cu 3 O 8+†" @default.
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- W2005461132 doi "https://doi.org/10.1016/0921-4534(89)91133-7" @default.
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