Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005464030> ?p ?o ?g. }
- W2005464030 endingPage "116" @default.
- W2005464030 startingPage "108" @default.
- W2005464030 abstract "The oxygen reduction reaction (ORR) on Pd–Co electro-catalyst has been studied in acidic media. The palladium alloys were prepared by coating glassy (GC) carbon substrates using a R-F magnetron sputtering equipment with a palladium and cobalt wafers as targets. The dual sputtering allowed us to obtain a thin film of 40–60 nm thick. The ORR kinetics was studied on these catalysts in 0.05 M H2SO4. An increase in the hydrogen adsorption charge, the oxide formation and the oxide reduction or desorption was observed with the Co content in the alloy for the alloys containing 20–84% of Co. It was further shown that the ORR on Pd–Co alloys proceeds through four transferred electrons mechanism and a Tafel slope of 60 mV/dec. The electro catalytic performance of the ORR on the various electrodes studied here is: in the order Pd16Co84 < Pd42Co58 < Pd < Pd50Co50 < Pd75Co25 < Pd65Co35 < Pt. This result clearly shows that alloying Pd with a specific composition of Co enhances significantly the electro-catalytic properties of the ORR on Pd–Co alloys in comparison to Pd alone. The enhancement of the electro catalytic activity is attributed to an optimal d band property that makes easier the OOH dissociative adsorption which is considered as chemical rate-determining step (RDS) for the ORR." @default.
- W2005464030 created "2016-06-24" @default.
- W2005464030 creator A5020744499 @default.
- W2005464030 creator A5034410684 @default.
- W2005464030 date "2013-08-01" @default.
- W2005464030 modified "2023-09-27" @default.
- W2005464030 title "Electrochemical investigation of Pd–Co thin films binary alloy for the oxygen reduction reaction in acid medium" @default.
- W2005464030 cites W1943672294 @default.
- W2005464030 cites W1967389887 @default.
- W2005464030 cites W1967554316 @default.
- W2005464030 cites W1970943729 @default.
- W2005464030 cites W1974562653 @default.
- W2005464030 cites W1978322412 @default.
- W2005464030 cites W1979771121 @default.
- W2005464030 cites W1980154070 @default.
- W2005464030 cites W1981712281 @default.
- W2005464030 cites W1982824609 @default.
- W2005464030 cites W1983372531 @default.
- W2005464030 cites W1984896739 @default.
- W2005464030 cites W1994054138 @default.
- W2005464030 cites W1995719798 @default.
- W2005464030 cites W2004640532 @default.
- W2005464030 cites W2034619601 @default.
- W2005464030 cites W2036569628 @default.
- W2005464030 cites W2046109518 @default.
- W2005464030 cites W2049280402 @default.
- W2005464030 cites W2061813474 @default.
- W2005464030 cites W2070537349 @default.
- W2005464030 cites W2070723593 @default.
- W2005464030 cites W2072851026 @default.
- W2005464030 cites W2082009562 @default.
- W2005464030 cites W2083145634 @default.
- W2005464030 cites W2085922483 @default.
- W2005464030 cites W2088845728 @default.
- W2005464030 cites W2092755206 @default.
- W2005464030 cites W2094712324 @default.
- W2005464030 cites W2096152070 @default.
- W2005464030 cites W2122838688 @default.
- W2005464030 cites W2129749999 @default.
- W2005464030 cites W2139253048 @default.
- W2005464030 cites W2140470873 @default.
- W2005464030 cites W2144585603 @default.
- W2005464030 cites W2158344334 @default.
- W2005464030 cites W2169670723 @default.
- W2005464030 doi "https://doi.org/10.1016/j.jelechem.2013.04.006" @default.
- W2005464030 hasPublicationYear "2013" @default.
- W2005464030 type Work @default.
- W2005464030 sameAs 2005464030 @default.
- W2005464030 citedByCount "16" @default.
- W2005464030 countsByYear W20054640302014 @default.
- W2005464030 countsByYear W20054640302015 @default.
- W2005464030 countsByYear W20054640302016 @default.
- W2005464030 countsByYear W20054640302017 @default.
- W2005464030 countsByYear W20054640302018 @default.
- W2005464030 countsByYear W20054640302020 @default.
- W2005464030 countsByYear W20054640302021 @default.
- W2005464030 countsByYear W20054640302022 @default.
- W2005464030 countsByYear W20054640302023 @default.
- W2005464030 crossrefType "journal-article" @default.
- W2005464030 hasAuthorship W2005464030A5020744499 @default.
- W2005464030 hasAuthorship W2005464030A5034410684 @default.
- W2005464030 hasConcept C127413603 @default.
- W2005464030 hasConcept C147789679 @default.
- W2005464030 hasConcept C150394285 @default.
- W2005464030 hasConcept C161790260 @default.
- W2005464030 hasConcept C172404476 @default.
- W2005464030 hasConcept C17525397 @default.
- W2005464030 hasConcept C178790620 @default.
- W2005464030 hasConcept C179104552 @default.
- W2005464030 hasConcept C185592680 @default.
- W2005464030 hasConcept C2777869211 @default.
- W2005464030 hasConcept C2779851234 @default.
- W2005464030 hasConcept C2780026712 @default.
- W2005464030 hasConcept C2781060269 @default.
- W2005464030 hasConcept C33989665 @default.
- W2005464030 hasConcept C42360764 @default.
- W2005464030 hasConcept C502130503 @default.
- W2005464030 hasConcept C512968161 @default.
- W2005464030 hasConcept C515602321 @default.
- W2005464030 hasConcept C52859227 @default.
- W2005464030 hasConceptScore W2005464030C127413603 @default.
- W2005464030 hasConceptScore W2005464030C147789679 @default.
- W2005464030 hasConceptScore W2005464030C150394285 @default.
- W2005464030 hasConceptScore W2005464030C161790260 @default.
- W2005464030 hasConceptScore W2005464030C172404476 @default.
- W2005464030 hasConceptScore W2005464030C17525397 @default.
- W2005464030 hasConceptScore W2005464030C178790620 @default.
- W2005464030 hasConceptScore W2005464030C179104552 @default.
- W2005464030 hasConceptScore W2005464030C185592680 @default.
- W2005464030 hasConceptScore W2005464030C2777869211 @default.
- W2005464030 hasConceptScore W2005464030C2779851234 @default.
- W2005464030 hasConceptScore W2005464030C2780026712 @default.
- W2005464030 hasConceptScore W2005464030C2781060269 @default.
- W2005464030 hasConceptScore W2005464030C33989665 @default.
- W2005464030 hasConceptScore W2005464030C42360764 @default.
- W2005464030 hasConceptScore W2005464030C502130503 @default.
- W2005464030 hasConceptScore W2005464030C512968161 @default.
- W2005464030 hasConceptScore W2005464030C515602321 @default.