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- W2005464685 abstract "Abstract Poly[10-(4′-octyloxyphenyl)-phenothiazine-3,7-diyl] (POPPTZ), poly[9,9-bis(4′-octyloxyphenyl)fluorene-2,7-diyl] (PBOPF), and their random copolymers, poly(BOPF- co -OPPTZ), were synthesized through Ni(0) mediated polymerization. Light-emitting devices were fabricated using these polymers in an ITO (indium-tin oxide)/PEDOT:PSS/polymer/Ca/Al configuration. Each EL device constructed with a poly(BOPF- co -OPPTZ) copolymer exhibited significantly enhanced efficiency and brightness compared to devices constructed from the POPPTZ and PBOPF homopolymers. The EL device constructed with poly(83BOPF- co -17OPPTZ) exhibited the highest power efficiency and brightness (8,610 cd/m 2 and 2.831 cd/A, respectively). This enhanced efficiency of the copolymer devices results from their improved hole injection and more efficient charge carrier balance, which arise due to the HOMO levels (∼5.42 eV) of the poly(BOPF- co -OPPTZ) copolymers, which are lower than that of the PBOPF homopolymer (∼5.79 eV)." @default.
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- W2005464685 date "2009-08-01" @default.
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- W2005464685 title "Synthesis and light-emitting properties of copolymers composed of fluorene and N-alkoxyphenylphenothiazine" @default.
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- W2005464685 doi "https://doi.org/10.1016/j.synthmet.2009.05.005" @default.
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