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- W2005476725 abstract "Mixtures of formic acid and water were insonated with 300 kHz ultrasonic waves under an atmosphere of argon. H2, CO2, CO and very small amounts of oxalic acid are the products. The oxalic acid yield decreases with increasing HCOOH concentration. However, the yields of the other products pass through a maximum at 15 M. A mechanism is discussed where the decomposition of HCOOH into radicals plays only a minor role, the main reactions being thermal dehydration. The reactions are attributed to the high temperatures which exist in the adiabatic compression phase of cavitating argon bubbles, the temperature becoming lower with increasing HCOOH content of the gas bubbles." @default.
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- W2005476725 date "1988-01-01" @default.
- W2005476725 modified "2023-09-26" @default.
- W2005476725 title "Sonolysis of formic acid-water mixtures" @default.
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- W2005476725 doi "https://doi.org/10.1016/1359-0197(88)90006-9" @default.
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