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- W2005482633 abstract "The process of morphology formation in a binary blend of poly(ε-caprolactone) homopolymer (PCL) and poly(ε-caprolactone)-block-polybutadiene copolymer (PCL-b-PB) has been investigated by synchrotron small-angle X-ray scattering (SR-SAXS). This blend shows an UCST-type phase separation and the crystallization of PCL chains (i.e., PCL and PCL blocks in PCL-b-PB) at a same temperature range, so that these two factors may work simultaneously to yield a complicated morphology formation. When the weight fraction of PCL (φPCL) is small (φPCL<0.2) or large (φPCL>0.8), the blend can directly be quenched into crystallization temperatures without passing through the UCST region. Time-resolved SAXS curves in this case show that overall morphology formation is driven by the crystallization of PCL chains, where a crystallized PCL region always coexists with a crystallized PCL-b-PB region and the volume ratio of two regions is constant throughout." @default.
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- W2005482633 date "2005-07-01" @default.
- W2005482633 modified "2023-10-17" @default.
- W2005482633 title "Synchrotron SAXS Studies on Morphology Formation in a Binary Blend of Poly(ε-caprolactone) Homopolymer and Poly(ε-caprolactone)-block-Polybutadiene Copolymer" @default.
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- W2005482633 doi "https://doi.org/10.1295/polymj.37.464" @default.
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