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- W2005525630 startingPage "1473" @default.
- W2005525630 abstract "The Wagner-Meerwein rearrangement of 9′-methyl-9,9′-bifluoren-9-ol yielded 10-(2,2′-biphenylylene)-9-methylenephenanthrene. Ozonolysis of the phenanthrene afforded 10-(2,2′-biphenylylene)-9-phenanthrone. This pinacolone was converted into 2′-(9-fluorenyl)biphenyl-2-carboxylic acid. Oxidation of 4,9′-bifluoren-9-one, which was obtained by ring closure of the acid, gave 9′-hydroxy-, 9′-benzyl-, and 9′-benzyloxy-4,9′-bifluoren-9-one. Isomers of 2,2′-diethyl-9,9′-bifluorene-9,9′-diol were obtained by reduction of 2-ethyl-9-fluorenone. The pinacols were rearranged to the corresponding pinacolones, which were cleaved into carboxylic acids. The structural assignment of these isomers was made by spectral analyses." @default.
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- W2005525630 date "1978-05-01" @default.
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- W2005525630 title "Syntheses and Reactions of 10-(2,2′-Biphenylylene)-9-phenanthrone Derivatives and Some Consideration of Ethyl Isomers in Their Analogous Series" @default.
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- W2005525630 doi "https://doi.org/10.1246/bcsj.51.1473" @default.
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