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• W2005561319 endingPage "4217" @default.
• W2005561319 startingPage "4212" @default.
• W2005561319 abstract "The enhanced reactivity exhibited by six pseudo-α-bases, RC≡CZ− (R = H and Cl; Z = O, S, and Se) in gas-phase E2 reactions with ethyl chloride was examined at the G2(+) level. It is found that anomalous reactivity is observed despite the fact that these chalcogen bases do not possess adjacent lone-pair electrons. The influence of the halide leaving groups on the α-effect and the origin of the α-effect in the E2 reactions of ethyl halides are investigated and discussed." @default.
• W2005561319 created "2016-06-24" @default.
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• W2005561319 date "2010-05-19" @default.
• W2005561319 modified "2023-09-25" @default.
• W2005561319 title "Enhanced Reactivity of RC≡CZ⁻ (R = H and Cl; Z = O, S, and Se) and the Influence of Leaving Group on the α-Effect in the E2 Reactions" @default.
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• W2005561319 doi "https://doi.org/10.1021/jo1006575" @default.
• W2005561319 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20481599" @default.
• W2005561319 hasPublicationYear "2010" @default.
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