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• W2005570215 abstract "The asymmetric total syntheses of (+)-curcutetraol and (+)-sydonol, phenolic bisabolane-type sesquiterpenoids having chiral tertiary alcohol moiety in the o-position of a phenol, were achieved in high enantiomeric excesses (99% ee). The chiral tertiary benzylic alcohol moiety of these compounds was constructed by an asymmetric synthesis using an easily available chiral aminal, (−)-(2R,5S)-2-methoxycarbonyl-3-phenyl-1,3-diazabicyclo[3.3.0]octane. The absolute configurations of both (+)-curcutetraol and (+)-sydonol have been assumed to be S-configuration based on the stereochemical course of the well established asymmetric synthesis used in the syntheses." @default.
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• W2005570215 date "2008-10-01" @default.
• W2005570215 modified "2023-09-27" @default.
• W2005570215 title "Asymmetric total synthesis of (+)-curcutetraol and (+)-sydonol" @default.
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• W2005570215 doi "https://doi.org/10.1016/j.tet.2008.08.012" @default.
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