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- W2005575896 abstract "Dithiocarbamato-Komplexe des Typs 1 und 2 mit zwei verschiedenen Substituenten am Stickstoff-atom sind chiral. Die bei tiefen Temperaturen 1H-NMR-spektroskopisch nachweisbaren Isomeren racemisieren bzw. epimerisieren bei Raumtemperatur infolge Rotation um die S2CNR2- Bindung. Metallzentrierte Umlagerungen sind nicht zu beobachten. Optically Active Transition Metal Complexes, XXXI. Racemization and Epimerization as a Consequence of the Rotation Around the S2CNR2 Bond in Dithiocarbamato Complexes Dithiocarbamato complexes of the type 1 and 2 with two different substituents at the nitrogen atom are chiral. The isomers, which can be identified at low temperatures by 1H n.m.r. spectroscopy, racemize or epimerize at room temperature as a consequence of a rotation around the S2CNR2 bond. Metal-centered rearrangements are not observed." @default.
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- W2005575896 date "1975-10-01" @default.
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- W2005575896 title "Optisch aktive Übergangsmetall‐Komplexe, XXXI. Racemisierung und Epimerisierung als Folge der Rotation um die S <sub>2</sub> CNR <sub>2</sub> ‐Bindung in Dithiocarbamato‐Komplexen" @default.
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- W2005575896 doi "https://doi.org/10.1002/cber.19751081027" @default.
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