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- W2005576085 abstract "In a paper submitted to the German Chemical Society about a year ago, we proved (Dr. Martius and myself) that the action of methylic alcohol on aniline chlorhydrate at a high temperature and under pressure, far from yielding exclusively methyl- and dimethylaniline, as had been formerly believed, is capable of causing methylation of the phenyl group, and thus producing quite a series of higher homologues of dimethylaniline. If we endeavour to gain an insight into the mechanism of this reaction, we are led to assume that in the first instance the chlorhydric acid of the aniline salt gives rise to the formation of methylic chloride, which in its turn induces substitution, first in the ammonia fragment, and ultimately in the phenyl group itself. If, on the other hand, we remember that a tertiary monamine, such as must be formed by the final methylation of the ammonia fragment in aniline, when submitted to the action of an alcohol chloride, is invariably converted into an ammonium compound, it must appear rather strange that, in the process above alluded to, only tertiary, and never any quartary bases are observed." @default.
- W2005576085 created "2016-06-24" @default.
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- W2005576085 date "1873-12-31" @default.
- W2005576085 modified "2023-09-24" @default.
- W2005576085 title "I. Synthesis of aromatic monamines by intramolecular atomic interchange" @default.
- W2005576085 doi "https://doi.org/10.1098/rspl.1872.0009" @default.
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