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- W2005577189 abstract "Abstract Comprehensive GC in the reversed polarity mode i.e . a polar main column and an apolar secondary column have been used to differentiate cyclic olefins, dienes and cyclic dienes in high temperature Fischer–Tropsch (FT)‐based fuels. The elucidation of the blobs in the contour plot was based on spectral data obtained by TOF‐MS. The effectiveness of selective catalytic hydrogenation in transforming dienes into olefins could be studied. Dienes are prone to polymerisation by Diels–Alder reactions and dimers and trimers were detected in the 2‐D plot by operating the MS in the ion extraction mode. Polymerisation is thought to be partially responsible for gum formation in high temperature FT‐derived products." @default.
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- W2005577189 date "2008-10-01" @default.
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- W2005577189 title "The use of GC×GC with time‐of‐flight mass spectrometry to investigate dienes and Diels–Alder polymerisation products in high‐temperature Fischer–Tropsch‐based fuels" @default.
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- W2005577189 doi "https://doi.org/10.1002/jssc.200800260" @default.
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