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- W2005603113 abstract "A.c. polarograms of nucleosides currently occurring in nucleic acids exhibit a minimum at a potential of about −0.4 V, caused by the adsorption of nucleosides on the electrode surface. At higher concentrations of deoxycytidine, adenosine, guanosine, and deoxyguanosine, association of the adsorbed molecules takes place in the neighbourhood of this potential. With deoxyadenosine, association of the molecules occurs at about a potential of −1.2 V. With adenosine, association occurs at both −0.4 V and −1.2 V, approximately. As with bases, the transition from the non-associated to the associated state occurs over a close concentration interval in which the adsorption isotherm has an inflection point. With uridine, thymidine, and cytidine, no association of the adsorbed molecules takes place under the given experimental conditions, even at concentrations approaching saturation value. At pH=7.0, most of the nucleosides tested are polarographically non-reducible and the maxima observed on the a.c. polarograms are of a capacitive character. Only the peak for cytidine and deoxycytidine at a potential of −1.6 V is caused by reduction of cytosine." @default.
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- W2005603113 date "1968-10-01" @default.
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- W2005603113 title "Alternating current polarography of nucleosides" @default.
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- W2005603113 doi "https://doi.org/10.1016/s0022-0728(68)80200-1" @default.
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